Publications

2024

130. A. Choi, A. Das, A. J. H. M. Meijer, I. Proietti Silvestri, I. Coldham, Org. Biomol. Chem. 2024, 22, 1602–1607.
'Synthesis of Enantioenriched Spirocyclic 2-Arylpiperidines via Kinetic Resolution'
DOI: 10.1039/D4OB00011KD

2023

129. Z. M. Cheema, M. Nisar, H. Y. Gondal, S. A. Al-Hussain, M. E. A. Zaki, I. Coldham, J. Saudi Chem. Soc. 2023, 27, 101746.
'New benzotriazole-derived alpha-substituted hemiaminal ethers with enhanced cholinesterase inhibition activity: Synthesis, structural, and biological evaluations'
DOI: 10.1016/j.jscs.2023.101746
128. S.-H. Yeo, A. Choi, S. Greaves, A. J. H. M. Meijer, I. Proietti Silvestri, I. Coldham, Chem. Eur. J. 2023, 29, e202300815.
'Kinetic Resolution of 2-Aryldihydroquinolines using Lithiation – Synthesis of Chiral 1,2- and 1,4-Dihydroquinolines'
DOI: 10.1002/chem.202300815
127. A. Das, A. Choi, I. Coldham, Org. Lett. 2023, 25, 987–991.
'Photocatalysis and Kinetic Resolution by Lithiation to give Enantioenriched 2-Arylpiperazines'
DOI: 10.1021/acs.orglett.3c00074

2022

126. A. Choi, A. J. H. M. Meijer, I. Proietti Silvestri, I. Coldham, J. Org. Chem. 2022, 87, 8819–8823.
'Kinetic Resolution of 2-Aryl-4-methylenepiperidines toward Enantioenriched Functionalizable Piperidine Fragments'
DOI: 10.1021/acs.joc.2c00862
125. A. El-Tunsi, N. Carter, S.-H. Yeo, J. D. Priest, A. Choi, C. M. Kobras, S. Ndlovu, I. Proietti Silvestri, A. K. Fenton, I. Coldham, Synthesis 2022, 54, 355–368.
'Kinetic Resolution by Lithiation: Highly Enantioselective Synthesis of Substituted Dihydrobenzoxazines and Tetrahydroquinoxalines'
DOI: 10.1055/a-1638-2478

2021

124. A. Choi, A. El-Tunsi, Y. Wang, A. J. H. M. Meijer, J. Li, X. Li, I. Proietti Silvestri, I. Coldham,
Chem. Eur. J. 2021, 27, 11670–11675.
'Asymmetric Synthesis of 2-Arylindolines and 2,2-Disubstituted Indolines by Kinetic Resolution'
DOI: 10.1002/chem.202101248

2020

123. A. K. Jayavelu, T. M. Schnöder, F. Perner, C. Herzog, A. Meiler, G. Krishnamoorthy, N. Huber, J. Mohr, B. Edelmann-Stephan, R. Austin, S. Brandt, F. Palandri, N. Schröder, B. Isermann, F. Edlich, A. U. Sinha, M. Ungelenk, C. A. Hübner, R. Zeiser, S. Rahmig, C. Waskow, I. Coldham, T. Ernst, A. Hochhaus, S. Jilg, P. J. Jost, A. Mullally, L. Bullinger, P. R. Mertens, S. W. Lane, M. Mann, F. H. Heidel, Nature 2020, 588, 157–163.
'Splicing factor YBX1 mediates persistence of JAK2-mutated neoplasms'
DOI: 10.1038/s41586-020-2968-3
122. V. K. Aggarwal, S. K. Armstrong, L. Caggiano, K. Chibale, J. Clayden, I. Coldham, N. Greeves, R. C. Hartley, J. G. Knight, N. Kuhnert, H. J. Mitchell, A. Nelson, P. O'Brien, S. P. Thomas, P. Wyatt, Org. Biomol. Chem. 2020, 18, 7236–7237.
'Stuart Warren (24 Dec 1938 - 22 Mar 2020)'
DOI: 10.1039/D0OB90121K
121. A. Choi, J. Castle, R. Saruengkhanphasit, I. Coldham, Synthesis 2020, 52, 1273–1278.
'Synthesis of Spirocyclic Amines by 1,3-Dipolar Cycloaddition of Azomethine Ylides and Azomethine Imines'
DOI: 10.1055/s-0039-1691588

2019

120. A. Choi, I. Coldham, Tetrahedron Lett. 2019, 60, 151023.
'Three-component couplings for the synthesis of pyrroloquinoxalinones by azomethine ylide 1,3-dipolar cycloaddition chemistry'
DOI: 10.1016/j.tetlet.2019.151023
119. R. A. Talk, A. El-Tunsi, C. C. Robertson, I. Coldham, Eur. J. Org. Chem. 2019, 5294–5301.
'Regioselective lithiation and electrophilic quench of N-Boc-3-phenyltetrahydroisoquinoline'
DOI: 10.1002/ejoc.201900238
118. A. Choi, R. M. Morley, I. Coldham, Beilstein J. Org. Chem. 2019, 15, 1480–1484.
'Synthesis of pyrrolo[1,2-a]quinolines by formal 1,3-dipolar cycloaddition reactions of quinolinium salts'
DOI: 10.3762/bjoc.15.149
117. I. Mannaerts, L. F. R. Thoen, N. Eysackers, F. J. Cubero, S. B. Leite, I. Coldham, I. Colle, C. Trautwein, L. A. van Grunsven, Cell Death Dis. 2019, 10, e98 (1–12).
'Unfolded protein response is an early, non-critical event during hepatic stellate cell activation'
DOI: 10.1038/s41419-019-1327-5
116. Z. T. I. Alkayar, I. Coldham, Org. Biomol. Chem. 2019, 17, 66–73.
'Cascade cyclization and intramolecular nitrone dipolar cycloaddition and formal synthesis of 19-hydroxyibogamine'
DOI: 10.1039/C8OB02839G

2018

115. T. Aeyad, C. G. Jones, I. Coldham, Eur. J. Org. Chem. 2018, 5289–5296.
'Preparation of Substituted Tetrahydro-1-benzazepines by Lithiation-Trapping'
DOI: 10.1002/ejoc.201800868
114. N. Carter, X. Li, L. Reavey, A. J. H. M. Meijer, I. Coldham, Chem. Sci. 2018, 9, 1352–1357.
'Synthesis and Kinetic Resolution of Substituted Tetrahydroquinolines by Lithiation then Electrophilic Quench'
DOI: 10.1039/C7SC04435F

2017

113. T. Aeyad, J. D. Williams, A. J. H. M. Meijer, I. Coldham, Synlett 2017, 28, 2765–2768.
'Lithiation–substitution of N-Boc-2-phenylazepane'
DOI: 10.1055/s-0036-1590857
112. R. Saruengkhanphasit, D. Collier, I. Coldham, J. Org. Chem. 2017, 82, 6489–6496.
'Synthesis of Spirocyclic Amines by Using Dipolar Cycloadditions of Nitrones'
DOI: 10.1021/acs.joc.7b00959
111. M. R. Alshawish, G. Barker, N. D. Measom , I. Coldham, Comptes Rendus Chimie 2017, 20, 601–608.
'Metallation–substitution of an alpha-oxygenated chiral nitrile'
DOI: 10.1016/j.crci.2016.11.006
110. A. Sadhukhan, M. C. Hobbs, A. J. H. M. Meijer, I. Coldham, Chem. Sci. 2017, 8, 1436–1441.
'Highly enantioselective metallation–substitution alpha to a chiral nitrile'
DOI: 10.1039/C6SC03712G
See highlight in Synform 2017, A80–A82.

2016

109. R. C. Furnival, R. Saruengkhanphasit, H. E. Holberry, J. R. Shewring, H. D. S. Guerrand, H. Adams, I. Coldham, Org. Biomol. Chem. 2016, 14, 10953–10962.
'Cascade oxime formation, cyclization to a nitrone, and intermolecular dipolar cycloaddition'
DOI: 10.1039/C6OB01871H
108. R. A. Talk, A. Duperray, X. Li, I. Coldham, Org. Biomol. Chem. 2016, 14, 4908–4917.
'Synthesis of substituted tetrahydroisoquinolines by lithiation then electrophilic quench'
DOI: 10.1039/C6OB00577B
107. V. J. B. Gotham, M. C. Hobbs, R. Burgin, D. Turton, C. Smythe, I. Coldham, Org. Biomol. Chem. 2016, 14, 1559–1563.
'Synthesis and activity of a novel inhibitor of nonsense-mediated mRNA decay'
DOI: 10.1039/C5OB02482J
106. Z. T. I. Alkayar, H. Adams, I. Coldham, Synlett 2016, 27, 447–449.
'Regiochemical and stereochemical studies of the intramolecular dipolar cycloaddition of nitrones derived from quaternary aldehydes'
DOI: 10.1055/s-0035-1560906

2015

105. I. Coldham and N. S. Sheikh, Applications of Domino Transformations in Organic Synthesis 2 (Science of Synthesis Reference Library 2015/4b), ed. S. A. Snyder, Georg Thieme Verlag KG, Stuttgart, 2015, ch. 2.1.2, pp 47–91.
'Domino reactions including [2+2], [3+2], or [5+2] cycloadditions'
ISBN: 978-3-13-221141-4
104. E. J. Cochrane, L. A. Hassall, I. Coldham, J. Org. Chem. 2015, 80, 5964–5969.
'Preparation of 1-substituted tetrahydro-beta-carbolines by lithiation–substitution'
DOI: 10.1021/acs.joc.5b00725
103. R. Pathak, B. C. Dobson, N. Ghosh, K. A. Ageel, M. R. Alshawish, R. Saruengkhanphasit, I. Coldham, Org. Biomol. Chem. 2015, 13, 3331–3340.
'Synthesis of the tricyclic core of manzamine A'
DOI: 10.1039/C4OB02582B

2014

102. E. J. Cochrane, D. Leonori, L. A. Hassall, I. Coldham, Chem. Commun. 2014, 50, 9910–9913.
'Synthesis and kinetic resolution of N-Boc-2-arylpiperidines'
DOI: 10.1039/c4cc04576a
101. X. Li, I. Coldham, J. Am. Chem. Soc. 2014, 136, 5551–5554.
'Synthesis of 1,1-Disubstituted Tetrahydroisoquinolines by Lithiation and Substitution, with in Situ IR Spectroscopy and Configurational Stability Studies'
DOI: 10.1021/ja500485f
100. D. Mortimer, M. Whiting, J. P. A. Harrity, S. Jones, I. Coldham, Tetrahedron Lett. 2014, 55, 1255–1257.
'Synthesis of an azabicyclic framework towards actinophyllic acid'
DOI: 10.1016/j.tetlet.2014.01.019
99. D. Nath, M. C. Skilbeck, I. Coldham, F. F. Fleming, Org. Lett. 2014, 16, 62–65.
'Arylthio-Metal Exchange of alpha-Arylthioalkanenitriles'
DOI: 10.1021/ol403020s 

2013

98. G. Barker, M. R. Alshawish, M. C. Skilbeck, I. Coldham, Angew. Chem. Int. Ed. 2013, 52, 7700–7703.
'Remarkable Configurational Stability of Magnesiated Nitriles'
DOI: 10.1002/anie.201303442
97. X. Li, D. Leonori, N. S. Sheikh, I. Coldham, Chem. Eur. J. 2013, 19, 7724–7730.
'Synthesis of 1-substituted tetrahydroisoquinolines by lithiation and electrophilic quench guided by in situ IR and NMR spectroscopy and application to the synthesis of salsolidine, carnegine and laudanosine'
DOI: 10.1002/chem.201301096
96. O. Garcia-Calvo, E. Coya, S. Lage, I. Coldham, N. Sotomayor, E. Lete, Eur. J. Org. Chem. 2013, 1460–1470.
'Intramolecular carbolithiation reactions in the construction of medium size rings. Synthesis of pyrroloisoquinolines, benzazepines and benzazocines'
DOI: 10.1002/ejoc.201200994

2012

95. I. Coldham, S. P. Robinson, C. A. Baxter, Synlett 2012, 23, 2405–2407.
'Asymmetric Synthesis of 2-Arylpyrrolidines by Cationic Cyclization'
DOI: 10.1055/s-0032-1317114
94. N. S. Sheikh, D. Leonori, G. Barker, J. D. Firth, K. R. Campos, A. J. H. M. Meijer, P. O'Brien, I. Coldham, J. Am. Chem. Soc. 2012, 134, 5300–5308.
'An Experimental and In Situ IR Spectroscopic Study of the Lithiation-Substitution of N-Boc 2-phenylpyrrolidine and piperidine: Controlling the Formation of Quaternary Stereocenters'
DOI: 10.1021/ja211398b
93. M. J. Thompson, J. C. Louth, S. M. Little, M. P. Jackson, Y. Boursereau, B. Chen, I. Coldham, Chem. Med. Chem. 2012, 7, 578–586.
'Synthesis and Evaluation of 1-Amino-6-halo-beta-carbolines as Antimalarial and Antiprion Agents'
DOI: 10.1002/cmdc.201200002
92. H. H. Ince, B. Dedeoglu, S. Gul, V. Aviyente, I. Coldham, Molecular Physics 2012, 110, 353–359.
'Selectivity in the aggregates of the chiral organolithium N-Boc-2-lithiopiperidine with a chiral ligand: A DFT study'
DOI: 10.1080/00268976.2011.647103
91. I. Coldham, A. J. M. Burrell, H. D. S. Guerrand, L. Watson, N. G. Martin, N. Oram, Beilstein J. Org. Chem. 2012, 8, 107–111.
'Synthesis of fused tricyclic amines unsubstituted at the ring-junction positions by a cascade condensation, cyclization, cycloaddition then decarbonylation strategy'
DOI: 10.3762/bjoc.8.11
90. I. Coldham, A. J. M. Burrell, L. Watson, N. Oram, N. G. Martin, Heterocycles 2012, 84, 597–613.
'Synthesis of fused tricyclic heterocycles by condensation, cyclization, dipolar cycloaddition cascade of alpha-benzenesulfonyl and alpha-phenylthio substituted aldehydes'
DOI: 10.3987/COM-11-S(P)29 

2011

89. H. D. S. Guerrand, H. Adams, I. Coldham, Org. Biomol. Chem. 2011, 9, 7921–7928.
'Cascade Cyclization, Dipolar Cycloaddition of Azomethine Imines for the Synthesis of Pyrazolidines'
DOI: 10.1039/C1OB06122D
88. M. J. Thompson, J. C. Louth, S. M. Little, B. Chen, I. Coldham, Bioorg. Med. Chem. Lett. 2011, 21, 3644–3647.
'2,4-Diarylthiazole antiprion compounds as a novel structural class of antimalarial leads'
DOI: 10.1016/j.bmcl.2011.04.090
87. I. Coldham, L. Watson, H. Adams, N. G. Martin, J. Org. Chem. 2011, 76, 2360–2366.
'Synthesis of the Core Ring System of the Yuzurimine Type Daphniphyllum Alkaloids by Cascade Condensation, Cyclization, Cycloaddition Chemistry'
DOI: 10.1021/jo2000868
86. I. Coldham, A. J. M. Burrell, H. D. S. Guerrand, N. Oram, Org. Lett. 2011, 13, 1267–1269.
'Cascade Cyclization, Dipolar Cycloaddition to Bridged Tricyclic Amines Related to the Daphniphyllum Alkaloids'
DOI: 10.1021/ol102961x
85. A. I. Franklin, D. Bensa, H. Adams, I. Coldham, Org. Biomol. Chem. 2011, 9, 1901–1907.
'Transannular dipolar cycloaddition as an approach towards the synthesis of the core ring system of the sarain alkaloids'
DOI: 10.1039/C0OB01019G
84. Kh. M. Shakhidoyatov, I. Coldham, T. F. Ibragimov, Chem. Nat. Compds. 2011, 46, 929–931.
'Lithiation of deoxypeganinine and chiral synthesis of deoxypeganine derivatives'
DOI: 10.1007/s10600-011-9785-8
83. O. Garcia-Calvo, N. Sotomayor, E. Lete, I. Coldham, Arkivoc 2011, v, 957–66.
'Organolithium or Heck-type cyclization of N-ortho-iodobenzyl-2-alkenylpyrrolidines to give indolizidines'
ISSN: 1551-7012, WB-5621EP

2010

82. A. J. M. Burrell, L. Watson, N. G. Martin, N. Oram, I. Coldham, Org. Biomol. Chem. 2010, 8, 4530–4532.
'Synthesis of the core ring system of the stemona alkaloids by cascade condensation, cyclization, intramolecular cycloaddition'
DOI: 10.1039/C0OB00408A
81. A. J. M. Burrell, I. Coldham, Curr. Org. Synth. 2010, 7, 312–331.
'Synthesis of Natural Products using Intramolecular Dipolar Cycloaddition Reactions'
ISSN: 1570-1794/10
80. I. Coldham, D. Leonori, J. Org. Chem. 2010, 75, 4069–4077.
'Regioselective and Stereoselective Copper(I)-Promoted Allylation and Conjugate Addition of N-Boc-2-lithiopyrrolidine and N-Boc-2-lithiopiperidine'
DOI: 10.1021/jo100415x
79. S. P. Robinson, N. S. Sheikh, C. A. Baxter, I. Coldham, Tetrahedron Lett. 2010, 51, 3642–3644.
'Dynamic thermodynamic resolution of lithiated N-Boc-N'-alkylpiperazines'
DOI: 10.1016/j.tetlet.2010.05.019
78. D. Stead, G. Carbone, P. O'Brien, K. R. Campos, I. Coldham, A. Sanderson, J. Am. Chem. Soc. 2010, 132, 7260–7261.
'Asymmetric Deprotonation of N-Boc Piperidine: React IR Monitoring and Mechanistic Aspects'
DOI: 10.1021/ja102043e
77. I. Coldham, H. Adams, N. J. Ashweek, T. A. Barker, A. T. Reeder, M. C. Skilbeck, Tetrahedron Lett. 2010, 51, 2457–2460.
'Synthesis of 2-hydroxy-3-indolinones and 3-hydroxy-2-indolinones by anionic cyclization, in situ oxidation and rearrangement'
DOI: 10.1016/j.tetlet.2010.02.159
76. I. Coldham, S. Raimbault, D. T. E. Whittaker, P. T. Chovatia, D. Leonori, J. J. Patel, N. S. Sheikh, Chem. Eur. J. 2010, 16, 4082–4090.
'Asymmetric Substitutions of 2-Lithiated N-Boc-piperidine and N-Boc-azepine by Dynamic Resolution'
DOI: 10.1002/chem.200903059
75. I. Coldham, N. S. Sheikh, Top. Stereochem. 2010, 26, 253–293.
'Dynamic Resolutions of Chiral Organolithiums'
ISBN 978-3-906390-61-1

2009

74. D. Leonori, I. Coldham, Adv. Synth. Cat. 2009, 351, 2619-2623.
'Direct Preparation of 7-Allyl- and 7-Arylindolines'
DOI: 10.1002/adsc.200900499
73. I. Coldham, D. Leonori, T. K. Beng, R. E. Gawley, Chem. Commun. 2009, 45, 5239–5241.
'The Barrier to Enantiomerization and Dynamic Resolution of N-Boc-2-lithiopiperidine and the Effect of TMEDA'
DOI: 10.1039/B911024K
72. T. K. Beng, T. I. Yousaf, I. Coldham, R. E. Gawley, J. Am. Chem. Soc. 2009, 131, 6908-6909.
'Enantiomerization Dynamics and a Catalytic Dynamic Resolution of N-Trimethylallyl-2-lithiopyrrolidine'
DOI: 10.1021/ja900755a
71. A. J. M. Burrell, I. Coldham, N. Oram, Org. Lett. 2009, 11, 1515–1518.
'Synthesis of Fused Tricyclic Amines from Enolisable Acyclic Aldehydes by Cyclization then Dipolar Cycloaddition Cascade: Synthesis of Myrioxazine A'
DOI: 10.1021/ol9001653
70. I. Coldham, S. Jana, L. Watson, N. G. Martin, Org. Biomol. Chem. 2009, 7, 1674–1679.
'Cascade condensation, cyclization, intermolecular dipolar cycloaddition by multi-component coupling and application to a synthesis of (±)-crispine A'
DOI: 10.1039/B822743H
69. A. J. M. Burrell, I. Coldham, L. Watson, N. Oram, C. D. Pilgram, N. G. Martin, J. Org. Chem. 2009, 74, 2290–2300.
'Stereoselective Formation of Fused Tricyclic Amines from Acyclic Aldehydes by a Cascade Process Involving Condensation, Cyclization and Dipolar Cycloaddition'
DOI: 10.1021/jo-2008-019913.R1

2008

68. I. Coldham, D. Leonori, Org. Lett. 2008, 10, 3923–3925.
'Synthesis of 2-Arylpiperidines by Palladium Couplings of Aryl Bromides with Organozinc Species Derived from Deprotonation of N-Boc-piperidine'
DOI: 10.1021/ol801579r
67. I. Coldham, S. Raimbault, P. T. Chovatia, J. J. Patel, D. Leonori, N. S. Sheikh, D. T. E. Whittaker, Chem. Commun. 2008, 44, 4174–4176.
'Dynamic Resolution of N-Boc-2-lithiopiperidine'
DOI: 10.1039/b810988e
66. I. Coldham, S. Jana, L. Watson, C. D. Pilgram, Tetrahedron Lett. 2008, 49, 5408–5410.
'Cascade Cyclization Intermolecular Dipolar Cycloaddition by Multi-component Couplings - Synthesis of Indolizidines and Pyrrolizidines'
DOI: 10.1016/j.tetlet.2008.07.010
65. D. Bensa, I. Coldham, P. Feinäugle, R. B. Pathak, R. J. Butlin, Org. Biomol. Chem. 2008, 6, 1410–1415.
'Synthesis of carboxylic amides by ring-opening of oxazolidinones with Grignard reagents'
DOI: 10.1039/b800849c
64. I. Coldham, J. J. Patel, S. Raimbault, D. T. E. Whittaker, H. Adams, G. Y. Fang, V. K. Aggarwal, Org. Lett. 2008, 10, 141–143.
'Asymmetric Lithiation–Substitution of Amines Involving Rearrangement of Borates'
DOI: 10.1021/ol702734u
63. T. I. Yousaf, R. L. Williams, I. Coldham, R. E. Gawley, Chem. Commun. 2008, 44, 97–98.
'The Barrier to Enantiomerization of N-Boc-2-lithiopyrrolidine: The Effect of Chiral and Achiral Diamines'
DOI: 10.1039/b714302h

2007

62. I. Coldham, J. J. Patel, S. Raimbault, D. T. E. Whittaker, Chem. Commun. 2007, 43, 4534–4536.
'Dynamic Kinetic and Kinetic Resolution of N-Boc-2-lithiopiperidine'
DOI: 10.1039/b710066c
61. I. Coldham, P. O'Brien, J. J. Patel, S. Raimbault, A. J. Sanderson, D. Stead, D. T. E. Whittaker, Tetrahedron: Asymmetry 2007, 18, 2113–2119.
'Asymmetric deprotonation of N-Boc-piperidines'
DOI: 10.1016/j.tetasy.2007.09.001
60. I. Coldham, A. J. M. Burrell, L. E. White, H. Adams, N. Oram, Angew. Chem. Int. Ed. 2007, 46, 6159–6162.
'Highly Efficient Synthesis of Tricyclic Amines by Cyclization/Cycloaddition Cascade: Total Syntheses of Aspidospermine, Aspidospermidine and Quebrachamine'
DOI: 10.1002/anie.200701943
59. I. Coldham, B. C. Dobson, S. R. Fletcher, A. I. Franklin, Eur. J. Org. Chem. 2007, 2676–2686.
'Intramolecular Dipolar Cycloaddition Reactions to give Substituted Indoles - a Formal Synthesis of Deethylibophyllidine'
DOI: 10.1002/ejoc.200700045
58. I. Coldham, B. C. Dobson, A. I. Franklin, S. R. Fletcher, Tetrahedron Lett. 2007, 48, 873–875.
'Synthesis of Tetracyclic Indole-containing Ring Systems by Intramolecular Cycloadditions of Azomethine Ylides'
DOI: 10.1016/j.tetlet.2006.11.130

2006

57. C. Stratmann, G. Christoph, I. Coldham, D. Hoppe, Org. Lett. 2006, 8, 4469–4471.
'Asymmetric Synthesis of 3-Hydroxy-pyrrolidines via Tin–Lithium Exchange and Cyclization'
DOI: 10.1021/ol061615p
56. I. Coldham, S. Dufour, T. F. N. Haxell, J. J. Patel, G. Sanchez-Jimenez, J. Am. Chem. Soc. 2006, 128, 10943–10951.
'Dynamic Thermodynamic and Dynamic Kinetic Resolution of 2-Lithiopyrrolidines'
DOI: 10.1021/ja061963m

2005

55. I. Coldham, R. Hufton, Chem. Rev. 2005, 105, 2765–2810.
'Intramolecular Dipolar Cycloaddition Reactions of Azomethine Ylides'
DOI: 10.1021/cr040004c
54. I. Coldham, S. M. Pih, R. Rabot, Synlett 2005, 1743–1745.
'Dipolar Cycloaddition and Ring-Closing Metathesis in the Synthesis of the Tetracyclic ABCE Ring System of Manzamine A'
DOI: 10.1055/s-2005-871538
53. I. Coldham, J. J. Patel, G. Sanchez-Jimenez, Chem. Commun. 2005, 41, 3083–3085.
'Dynamic Kinetic Resolution of N-Boc-2-lithiopyrrolidine'
DOI: 10.1039/B504015A
52. R. E. Gawley, R. Klein, N. J. Ashweek, I. Coldham, Tetrahedron 2005, 61, 3271–3280.
'NMR Structural Studies of {6Li} 2-Lithiopyrrolidines'
DOI: 10.1016/j.tet.2005.01.098
51. I. Coldham, S. Dufour, T. F. N. Haxell, G. P. Vennall, Tetrahedron 2005, 61, 3205–3220.
'Dynamic Resolution of N-Alkyl-2-lithiopyrrolidines with the Chiral Ligand (–)-Sparteine'
DOI: 10.1016/j.tet.2005.01.096
50. N. J. Ashweek, P. Brandt, I. Coldham, S. Dufour, R. E. Gawley, F. Haeffner, R. Klein, G. Sanchez-Jimenez, J. Am. Chem. Soc. 2005, 127, 449–457.
'The Barrier to Enantiomerization of Unstabilized, Chelated, and Dipole-Stabilized 2-Lithiopyrrolidines'
DOI: 10.1021/ja048090l

2004

49. W. Carruthers, I. Coldham, 'Modern Methods of Organic Synthesis'
4th edition, CUP, Cambridge, 2004 (493 printed pages)
ISBN 9780521778305
48. Y. Boursereau, I. Coldham, Bioorg. Med. Chem. Lett. 2004, 14, 5841–5844.
'Synthesis and Biological Studies of 1-Amino beta-Carbolines'
DOI: 10.1016/j.bmcl.2004.09.036
47. R. E. Gawley, I. Coldham, 'The Chemistry of Organolithium Compounds'
eds. Z. Rappoport, I. Marek, Wiley, 2004, Ch. 16, p. 997–1053.
'α-Amino-organolithium Compounds'
ISBN 978-0-470-84339-0

2003

46. I. Coldham, K. N. Price, R. E. Rathmell, Org. Biomol. Chem. 2003, 1, 2111–2119.
'Intramolecular Carbolithiation Reactions for the Preparation of 3-Alkenylpyrrolidines'
DOI: 10.1039/B303670G
45. N. J. Ashweek, I. Coldham, T. F. N. Haxell, S. Howard, Org. Biomol. Chem. 2003, 1, 1532–1544.
'Preparation of Diamines by Lithiation–Substitution of Imidazolidines and Pyrimidines'
DOI: 10.1039/B301502E

2002

44. I. Coldham, S. Dufour, T. F. N. Haxell, S. Howard, G. P. Vennall, Angew. Chem. Int. Ed. 2002, 41, 3887–3889.
'Enantioselective Synthesis of Substituted Pyrrolidines by Dynamic Resolution'
DOI: 10.1002/1521-3773(20021018)41:20<3887::AID-ANIE3887>3.0.CO;2-J
43. I. Coldham, K. M. Crapnell, J.-C. Fernandez, J. D. Moseley, R. Rabot, J. Org. Chem. 2002, 67, 6181–6187.
'Synthesis of the ABC Ring System of Manzamine A'
DOI: 10.1021/jo016376s
42. I. Coldham, G.P. Vennall, 'Science of Synthesis'
eds. E. J. Thomas and M. Moloney, Georg Thieme Verlag, 2002, Vol. 5, p. 451–461.
'1-Halo-, 1-Hydroxy-, 1-Alkoxy-, and 1-Aminoalkylstannanes'
ISBN 978-0-865-77944-0
41. I. Coldham, G.P. Vennall, 'Science of Synthesis'
eds. E. J. Thomas and M. Moloney, Georg Thieme Verlag, 2002, Vol. 5, p. 441–450.
'1-Halo-, 1-Alkoxy-, and 1-Aminovinylstannanes'
ISBN 978-0-865-77944-0
40. N. J. Ashweek, I. Coldham, D. J. Snowden, G. P. Vennall, Chem. Eur. J. 2002, 8, 195–207.
'Intramolecular Carbolithiation Reactions of Chiral α-Amino-organolithium Species'
DOI: 10.1002/1521-3765(20020104)8:1<195::AID-CHEM195>3.0.CO;2-H

2001

39. I. Coldham, R. C. B. Copley, T. F. N. Haxell, S. Howard, Org. Lett. 2001, 3, 3799–3801.
'Synthesis of Chiral 1,2-Diamines by Asymmetric Lithiation–Substitution'
DOI: 10.1021/ol016818m
38. I. Coldham, K. M. Crapnell, J. D. Moseley, R. Rabot, J. Chem. Soc., Perkin Trans. 1 2001, 1758–1763.
'Intramolecular Azomethine Ylide Cycloaddition Reactions to give Octahydroindoles'
DOI: 10.1039/B104390K
37. I. Coldham, R. Hufton, K. N. Price, R. E. Rathmell, D. J. Snowden and G. P. Vennall, Synthesis 2001, 1523–1531.
'Stereoselective Synthesis of Pyrrolidines and Pyrrolizidines by Intramolecular Carbolithiation'
DOI: 10.1055/s-2001-16074

2000

36. I. Coldham, G.P. Vennall, Chem. Commun. 2000, 1569–1570.
'Chiral Organolithium Species: Determination of the Rate of Cyclization and Extent of Racemization'
DOI: 10.1039/B004519P
35. I. Coldham, J.-C. Fernandez, K. N. Price, D. J. Snowden, J. Org. Chem. 2000, 65, 3788–3795.
'Intramolecular Carbolithiation Reactions for the Preparation of Azabicyclo[2.2.1]heptanes'
DOI: 10.1021/jo000088z
34. N. J. Ashweek, I. Coldham, G. P. Vennall, Tetrahedron Lett. 2000, 41, 2235–2237.
'A Convenient Route to N-Alkyl-2-tributylstannyl-pyrrolidines Involving Reductive Amination'
DOI: 10.1016/S0040-4039(00)00137-4
33. A. P. A. Arboré, D. J. Cane-Honeysett, I. Coldham, M. L. Middleton, Synlett 2000, 236–238.
'A Rapid Approach to Amino-Acid Derivatives by [2,3]-Stevens Rearrangement'
DOI: 10.1055/s-2000-6494

Pre-2000

32. I. Coldham, S. J. Coles, K. M. Crapnell, J.-C. Fernandez, T. F. N. Haxell, M. B. Hursthouse, J. D. Moseley, A. B. Treacy, Chem. Commun. 1999, 1757–1758.
'A New, Stereoselective Approach to the Manzamine Alkaloids'
31. J. E. H. Buston, I. Coldham, K. R. Mulholland, J. Chem. Soc., Perkin Trans. 1 1999, 2327–2334.
'Meisenheimer Rearrangements of N-Allyl 2-Azabornane Derivatives'
30. I. Coldham, J.-C. Fernandez, D. J. Snowden, Tetrahedron Lett. 1999, 40, 1819–1822.
'Synthesis of 7-Azabicyclo[2.2.1]heptanes by Anionic Cyclization'
29. I. Coldham, R. A. Judkins, D. R. Witty, Tetrahedron 1998, 54, 14255–14264.
'Proton Abstraction and Electrophilic Quench at C-2 of Imidazolidines'
28. I. Coldham, M. L. Middleton, P. L. Taylor, J. Chem. Soc., Perkin Trans. 1 1998, 2817–2821.
'Investigations into the [2,3]-Aza-Wittig Rearrangement of N-Alkyl N-Allyl α-Amino Esters'
27. J. E. H. Buston, I. Coldham, K. R. Mulholland, Tetrahedron: Asymmetry 1998, 9, 1995–2009.
'Studies into the Asymmetric Meisenheimer Rearrangement'
26. I. Coldham, P. M. A. Houdayer, R. A. Judkins, D. R. Witty, Synthesis 1998, 1463–1466.
'N,N'-Bisacylimidazolidines from 1,2-Diamines'
25. I. Coldham, J. Chem. Soc., Perkin Trans. 1 1998, 1343–1364.
'Main Group Organometallics in Synthesis'
24. I. Coldham, M. M. S. Lang-Anderson, R. E. Rathmell, D. J. Snowden, Tetrahedron Lett. 1997, 38, 7621–7624.
'Synthesis of Pyrrolidines by Anionic Cyclization onto Allylic Ethers, Alkynes and Carboxylic Groups'
23. I. Coldham, R. Hufton, R. E. Rathmell, Tetrahedron Lett. 1997, 38, 7617–7620.
'Stereoselective Anionic Cyclizations to Pyrrolidines'
22. I. Coldham, M. L. Middleton, P. L. Taylor, J. Chem. Soc., Perkin Trans. 1 1997, 2951–2952.
'N-Alkylation and [2,3]-Sigmatropic Rearrangement of N-Allyl α-Amino Esters'
21. I. Coldham, S. Holman, M. M. S. Lang-Anderson, J. Chem. Soc., Perkin Trans. 1 1997, 1481–1485.
'Preparation of β-Amino-alcohols by Carbon-Carbon Bond Formation using Substituted Lithiomethylpyrrolidines'
20. I. Coldham, Contemporary Organic Synthesis 1997, 136–163.
'Main Group Organometallics in Synthesis'
19. J. E. H. Buston, I. Coldham, K. R. Mulholland, Synlett 1997, 322–324.
'Chirality Transfer from Nitrogen to Carbon in the [2,3]-Meisenheimer Rearrangement'
18. I. Coldham, P. M. A. Houdayer, R. A. Judkins, D. R. Witty, Synlett 1996, 1109–1111.
'One-Pot Synthesis of N,N'-Bisacylimidazolidines; Potential New Acyl Anion Equivalents'
17. I. Coldham, R. Hufton, Tetrahedron 1996, 52, 12541–12552.
'Synthesis of 3-Alkylpyrrolidines by Anionic Cyclization'
16. I. Coldham, A. J. Collis, R. J. Mould, Electronic Conference on Heterocyclic Chemistry eds. H. Rzepa and J. Snyder, 1996, page:
http://www.ch.ic.ac.uk/ectoc/echet96/papers/012
'Vinylaziridines from vinylepoxides'
15. I. Coldham, R. Hufton, D. J. Snowden, J. Am. Chem. Soc. 1996, 118, 5322–5323.
'Anionic Cyclizations of α-Aminoorganolithiums. Determination of the Stereoselectivity at the Carbanion Center and the Synthesis of (+)-Pseudoheliotridane'
14. I. Coldham, A. J. Collis, R. J. Mould, R. E. Rathmell, J. Chem. Soc., Perkin Trans. 1 1995, 2739–2745.
'Synthesis of 4-Phenylpiperidines by tandem Wittig Olefination-Aza-Wittig Rearrangement of 2-Benzoylaziridines'
13. I. Coldham, A. J. Collis, R. J. Mould, D. E. Robinson, Synthesis 1995, 1147–1150.
'Pyrrolidines by 1,3-Dipolar Cycloaddition of Conjugated Azomethine Ylides'
12. I. Coldham, A. J. Collis, R. J. Mould, R. E. Rathmell, Tetrahedron Lett. 1995, 36, 3557–3560.
'Ring Expansion of Aziridines to Piperidines using the Aza-Wittig Rearrangement'
11. I. Coldham, R. Hufton, Tetrahedron Lett. 1995, 36, 2157–2160.
'A New Route to Cyclic Amines by Anionic Cyclization'
10. I. Coldham, 'Comprehensive Organic Functional Group Transformations'
eds. A. R. Katritzky, O. Meth-Cohn and C. W. Rees, Pergamon, Oxford, 1995, Vol. 1, p. 377–423.
'One or More CH and/or CC Bond(s) by Rearrangement'
9. P. Magnus, J. Lacour, I. Coldham, B. Mugrage, W. B. Bauta, Tetrahedron 1995, 51, 11087–11100.
'New Trialkylsilyl Enol Ether Chemistry: α-N-Tosylamination of Triisopropylsilyl Enol Ethers'
8. I. Coldham, J. Chem. Soc., Perkin Trans. 1 1993, 1275–1276.
'Aza-Wittig Rearrangements and Cyclizations by Transmetallation of N-Benzylaminomethylstannanes'
7. I. Coldham, S. Warren, J. Chem. Soc., Perkin Trans. 1 1993, 1637–1656.
'Synthesis of Cyclic Amines and Allylic Sulfides by Phenylthio Migration of β-Hydroxy Sulfides'
6. I. Coldham, S. Warren, J. Chem. Soc., Perkin Trans. 1 1993, 2303–2307.
'Stereospecific Phenylthio Migrations in the Synthesis of Spirocyclic Lactones and Ethers from N-Methyl-4-Piperidone and Quinuclidin-3-one'
5. P. Magnus, I. Coldham, J. Am. Chem. Soc. 1991, 113, 672–673.
'New Trialkylsilyl Enol Ether Chemistry. Synthesis of the Benzomorphanone Core Structure Using a Stereoelectronic Conformational Lock'
4. V. K. Aggarwal, I. Coldham, S. McIntyre, S. Warren, J. Chem. Soc., Perkin Trans. 1 1991, 451–460.
'Transformation of Cyclic α-Phenylthio Aldehydes by Stereoselective Aldol Reactions and Phenylthio Migration into Spirocyclic Lactones and Ethers, and E-Allylic Alcohols with 1,4-Related Chiral Centres'
3. I. Coldham, S. Warren, Tetrahedron Lett. 1989, 30, 5937–5940.
'Stereocontrolled Amidocyclizations with Phenylthio Migration'
2. I. Coldham, E. W. Collington, P. Hallett, S. Warren, Tetrahedron Lett. 1988, 29, 5321–5324.
'Stereochemically Controlled Synthesis of Spirocyclic Lactones and Ethers from N-Methyl-4-Piperidone and 3-Quinuclidinone by Phenylthio Migration'
1. V. K. Aggarwal, I. Coldham, S. McIntyre, F. H. Sansbury, M.-J. Villa, S. Warren, Tetrahedron Lett. 1988, 29, 4885–4888.
'Stereochemical Control in the Synthesis of Tetrahydrofurans by Cyclization of Diols with Phenylthio Migration'